郭玉国（中国硅酸盐学会固态离子学分会理事）

姓名：郭玉国

性别：男

职业：研究员，博士生导师，课题组长，中国硅酸盐学会固态离子学分会理事

获2008年度 “中国化学会青年化学奖”；2009年SCOPUS寻找未来科学之星纳米科学领域金奖

学历

1994-1998 青岛大学，获学士学位

1998-2001 青岛大学，获硕士学位（期间的研究工作在北京大学化学与分子工程学院物理化学研究所完成）

2001-2004 中国科学院化学研究所，获博士学位

学位-- 理学博士学位

出国学习工作2004-2006 Postdoc., Max Planck Institute for Solid State Research, Germany

2006-2007 Staff Scientist, Max Planck Institute for Solid State Research, Germany

1. 纳米能源材料与新能源器件（锂离子电池、锂硫电池、太阳能电池、燃料电池、超级电容器等）

2. 纳米体系离子、电子存储与输运（纳米离子学、纳米电化学）

3. 功能纳米材料与纳米器件

承担国家自然基金重点项目、中国科学院知识创新工程重要方向项目、北京市科委项目、企业合作研发横向项目等课题。另外，还得到化学所“引进杰出青年人才计划”和中科院优秀博士学位论文获得者科研启动专项资金的资助。

研究工作主要集中在能量转化与储存器件（锂离子电池、燃料电池等）中的电极、电解质和能量转化催化剂三类关键能源材料上，系统研究了纳米能源材料的热力学、动力学与表界面稳定性问题，以及纳米体系离子、电子存储与输运过程中的尺寸效应，探索出调控和解决途径。

（1）提出“分级三维混合导电网络”指导下高功率电极材料设计的新思想，在该思想指导下设计并成功制备出几种具有这种结构特征的、性能优异的新型纳微结构正负极材料，如：纳微结构合金复合负极材料、同轴电缆结构电极材料等。

（2）在电动汽车用锂离子动力电池用纳米磷酸铁锂正极材料研究方面取得了重要突破，成功研制出具有超快速充放电特性的磷酸铁锂纳微结构正极材料。目前正和企业一起进行材料的中试和规模化生产研究。

（3）通过纳微结构设计和电极材料表面包覆，部分解决了纳米储锂电极材料的表/界面稳定性问题，大幅提高了电极材料的容量和循环次数。

（4）发展了一种纳米体系离子电导原位测量技术，制备出新型高离子电导纳米电解质材料，发现纳米固体电解质的介观离子电导效应和异常电导各向同性现象，组装出纳米电池。

（5）开发了构筑纳米能源材料的多种创新方法，如：建立了普适的由微米原料制纳米产品的“自上而下”的电化学锂化法用于制备多孔纳米材料。

在Nature Mater.、Adv. Mater.、J. Am. Chem. Soc.等期刊上发表SCI论文60余篇，其中影响因子大于8.0的论文18篇，包括：Nature Mater.1篇（通讯作者文章）、Adv. Mater.12篇（8篇为第一/通讯作者论文）、JACS3篇（2篇为通讯作者论文）；影响因子大于5.0的论文30篇（22篇为第一/通讯作者论文）；影响因子大于3.0的论文51篇（38篇为第一/通讯作者论文）。这些论文2005年后被他人SCI引用1500多次，还有论文被ISI评为引用的Top1%。目前SCI上的H因子为21（即，有21篇发表的论文至少被引用21次）。申请国际和欧洲发明专利3项，中国发明专利10项，获授权2项。研究结果多次被美国材料研究学会、美国化学会、德国马普学会、英国皇家化学会Chemistry World、Nature China、Nanowerk、New Materials Asia、Green Car Congress、Frost & Sullivan、《科学通报》、《Bulletin of the Chinese Academy of Sciences》、《中国锂电材料信息导报》等机构、网站和杂志评述和报道。在国际/国内学术会议上作邀请报告10余次，得到了国内外同行较高的评价。由于在上述领域的研究影响，Advanced Materials杂志两次邀请撰写纳米能源材料相关综述文章和研究论文。其中发表在2008年第20卷第15期的研究进展文章被选为当期卷内插画，成为2008年8月份和2008全年度Most-Accessed文章之一，2009年还被评为The Best ofAdvanced Materials论文之一。

发表论文：

2011

1. F.-F. Cao, S. Xin, Y.-G. Guo* and L.-J. Wan*

Better lithium-ion batteries with nanocable-like electrode materials

Energy. Environ. Sci., 2011, 4, 1634-1642. (invited Perspective)

2. F.-F. Cao, S. Xin, Y.-G. Guo* and L.-J. Wan*

Wet chemical synthesis of Cu/TiO2 nanocomposites with integrated nano-current-collectors as high-rate anode materials in lithium-ion batteries

Phys. Chem. Chem. Phys. 2011, 13, 2014-2020

3. Y.-X. Yin, L.-Y. Jiang, L.-J. Wan, C.-J. Li,* Y.-G. Guo*

Polyethylene glyol-directed SnO2 nanowires for enhanced gas-sensing properties

Nanoscale, 2011, 3 (4), 1802 - 1806

4. X.-L. Wu, S. Xin, H.-H. Seo, J. Kim, Y.-G. Guo*, J.-S. Lee,*

Enhanced Li+ conductivity in PEO-LiBOB polymer electrolytes by using succinonitrile as a plasticizer

Solid State Ionics, 2011, 186, 1-6

5. X.-L. Wu, W. Wang, Y.-G. Guo* and L.-J. Wan

Template-Free Synthesis and Supercapacitance Performance of a Hierachically Porous Oxygen-Enriched Carbon Material

J. Nanosci. Nanotechnol., 2011, 11, 1897-1904

6. R.-R. Bi, Y.-X. Yin, Y.-G. Guo* and L.-J. Wan*

Synthesis of Flake-Like MnO2/CNT Composite Nanotubes and Their Applications in Electrochemical Capacitors

J. Nanosci. Nanotechnol., 2011, 11, 1996-2002

7. W. Guo, S. Xin, M.B. Ji, Y.-G. Guo*, L.J. Wan

Supercapacitor-battery hybrid energy storage devices from an aqueous nitroxide radical active material

Chin. Sci. Bull., 2011, in press.

8. 王建军, 郭玉国，万立骏*

质量比对基于CuInSe2/P3HT纳米复合材料光检测器件性能的影响

高等学校化学学报, 2011, 32(3), 726-730

9. Jian-Jun Wang, Yong-Qing Wang, Fei-Fei Cao, Yu-Guo Guo* and Li-Jun Wan*

Synthesis of Monodispersed Wurtzite Structure CuInSe2 Nanocrystals and Their Application in High Performance Organic-Inorganic Hybrid Photodetectors

J. Am. Chem. Soc., 2010, 132, 12218-12221

10. H.-X. Ji, X.-L. Wu, L.-Z. Fan, C. Krien, I. Fiering, Y.-G. Guo*, Y.F. Mei,* and O. G. Schmidt

Self-wound Composite Nanomembranes as Electrode Materials for Lithium Ion Batteries

Adv. Mater., 2010, 22, 4591-4595

11. Ling-Yan Jiang, Sen Xin, Xing-Long Wu, Hong Li, Yu-Guo Guo* and L.J. Wan

Non-sacrificial template synthesis of Cr2O3-C hierarchical core/shell nanospheres and their application as anode materials in lithium-ion batteries

J. Mater. Chem., 2010, 20, 7565-7569

12. F.F. Cao, X.L. Wu, S. Xin, Y.G. Guo* and L.J. Wan*

Facile Synthesis of Mesoporous TiO2-C Nanosphere as an Improved Anode Material for Superior High Rate 1.5V Rechargeable Li-Ion Batteries Containing LiFePO4-C Cathode

J. Phys. Chem. C, 2010, 114, 10308–10313

13. F. F. Cao, Y. G. Guo*, S. F. Zheng, X. L. Wu, L. Y. Jiang, R. R. Bi, L. J. Wan* and J. Maier*

Symbiotic Coaxial Nanocables: Facile Synthesis and an Efficient and Elegant Morphological Solution to the Lithium Storage Problem

Chem. Mater., 2010, 22, 1908-1914（英国皇家化学会Chemistry World评述）

14. L. S. Zhang, L. Y. Jiang, C. Q. Chen, W. Li, W. G. Song*, Y. G. Guo*

Programmed Fabrication of Metal Oxides Nanostructures Using Dual Templates to Spatially Disperse Metal Oxide Nanocrystals

Chem. Mater., 2010, 22, 414-419

15. R. R. Bi, X. L. Wu, F. F. Cao, L. Y. Jiang, Y. G. Guo*, L. J. Wan*

Highly Dispersed RuO2 Nanoparticles on Carbon Nanotubes: Facile Synthesis and Enhanced Supercapacitance Performance

J. Phys. Chem. C, 2010, 114, 2448-2451

16. X.L. Wu, L.L. Chen, S. Xin, Y.X. Yin, Y.G. Guo*, Q.S. Kong and Y.Z. Xia

Preparation and Li Storage Properties of Hierarchical Porous Carbon Fibers Derived from Alginic Acid

ChemSusChem, 2010, 3(6), 703 – 707

17. Bao Wang, Xing-Long Wu, Chun-Ying Shu, Yu-Guo Guo* and Chun-Ru Wang*

Synthesis of CuO/graphene nanocomposite as a high-performance anode material for lithium-ion batteries

J. Mater. Chem., 2010, 20, 10661-10664

18. L.S. Zhang, L.Y. Jiang, H.J. Yan, W.D. Wang, W.G. Song*, Y.G. Guo* and L.J. Wan

Mono dispersed SnO2 nanoparticles on both sides of single layer graphene sheets as anode materials in Li-ion batteries

J. Mater. Chem., 2010, 20, 5462–5467

19. X. Wang, X.-L. Wu, Y.-G. Guo, Y. Zhong, X. Cao, Y. Ma and J. Yao*

Synthesis and Lithium Storage Properties of Co3O4 Nanosheet-Assembled Multishelled Hollow Spheres

Adv. Funct. Mater., 2010, 20, 1680-1686

20. L.-L. Chen, X.-L. Wu, Y.-G. Guo*, Q.-S. Kong, Y.-Z. Xia*

Synthesis of Nanostructured Fibers Consisting of Carbon Coated Mn3O4 Nanoparticles and Their Application in Electrochemical Capacitors

J. Nanosci. Nanotechnol., 2010, 10(12) , 8158-8163

21. Hongwei Tang, Lili Chen, Chengfen Xing, Yu-Guo Guo*, Shu Wang*

DNA-templated synthesis of cationic poly(3,4-ethylenedioxythiophene) derivative for supercapacitor electrodes

Macromol. Rapid Commun. 2010, 31, 1892-1896

22. J.-S. Lee*, J.-W. Lee, J. Y. Lee, S. Adams, Y.-G. Guo, J. Maier

Microscopic Evidence of a New 9R-AgI Polytype Heterostructure

J. Nanosci. Nanotechnol., 2010, 10(5), 3341-3345

23. 郭玉国*，王忠丽，吴兴隆，张伟明，万立骏*

锂离子电池纳微结构电极材料系列研究

电化学, 2010, 16(2), 119-124 (中国电化学研究工作系列介绍，特约稿)

24. 樊博，郭玉国，万立骏*

Pt基电催化材料

化学进展, 2010, 22(5), 852-860

18. X. L. Wu, L. Y. Jiang, F. F. Cao,Y.-G. Guo,*L. J. Wan*

LiFePO4 Nanoparticles Embedded in a Nanoporous Carbon Matrix: Superior Cathode Material for Electrochemical Energy-Storage Devices

Adv. Mater.,2009, 21, 2710-2714.

19. J. J. Wang, F. F. Cao, L. Jiang,Y. G. Guo*, W. P. Hu*, L. J. Wan*

High Performance Photodetectors of Individual InSe Single Crystalline Nanowire

J. Am. Chem. Soc.,2009,131, 15602-15603 （Nature China评述）

20. X. L. Wu, Q. Liu,Y. G. Guo*,W. G. Song*

Superior storage performance of carbon nanosprings as anode materials for lithium-ion batteries

Electrochem. Commun.,2009,11,

21. L. Y. Jiang, X. L. Wu,Y. G. Guo*,L. J. Wan*

SnO2-Based Hierarchical Nanomicrostructures: Facile Synthesis and Their Applications in Gas Sensors and Lithium-Ion Batteries

J. Phys. Chem. C2009,113,

22. X. Wang, L. J. Yu, X. L. Wu, F. L. Yuan,Y. G. Guo, Y. Ma, Jian-Nian Yao*

Synthesis of Single-Crystalline Co3O4 Octahedral Cages with Tunable Surface Aperture and Their Lithium Storage Properties

J. Phys. Chem. C2009,113,

23. Zhi-Min Cui, Ling-Yan Jiang, Wei-Guo Song,* andYu-Guo Guo*

High-Yield Gas-Liquid Interfacial Synthesis of Highly Dispersed Fe3O4 Nanocrystals and Their Application in Lithium-Ion Batteries

Chem. Mater.,2009,21, 1162-1166

24. Hui Yang, Xing-Long Wu, Min-Hua Cao,* andYu-Guo Guo*

Solvothermal Synthesis of LiFePO4 Hierarchically Dumbbell-Like Microstructures by Nanoplate Self-Assembly and Their Application as a Cathode Material in Lithium-Ion Batteries

J. Phys. Chem. C,2009, 113 (8), 3345-3351.

25. Yu-Guo Guo, Jin-Song Hu and Li-Jun Wan

Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices

Adv. Mater.,2008, 20(15), 2878-2887. (Progress Report)

26. Wei-Ming Zhang, Jin-Song Hu,Yu-Guo Guo, Shu-Fa Zheng, Liang-Shu Zhong, Wei-Guo Song, and Li-Jun Wan*

Tin-nanoparticles encapsulated elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries

Adv. Mater.,2008, 20(6), 1160-1165.

27. Wei-Ming Zhang, Xing-Long Wu, Jin-Song Hu,Yu-Guo Guo,*and Li-Jun Wan*

Carbon Coated Fe3O4 Nanospindles as a Superior Anode Material for Lithium-Ion Batteries

Adv. Funct. Mater.,2008, 18, (24), 3941-3946.

28. Shu-Fa Zheng, Jin-Song Hu, Liang-Shu Zhong, Wei-Guo Song, Li-Jun Wan* andYu-Guo Guo*

Introducing dual functional CNT networks into CuO nanomicrospheres toward superior electrode materials for lithium-ion batteries

Chem. Mater.,2008, 20, (11), 3617-3622.

29. Heng-Xing Ji, Jin-Song Hu,Yu-Guo Guo*, Wei-Guo Song and Li-Jun Wan*

Ion-Transfer Based Growth: A Novel Mechanism of CuTCNQ Nanowire Formation

Adv. Mater.,2008, 20(24), 4879-4882

30. Xing-Long Wu,Yu-Guo Guo*, Li-Jun Wan and Chang-Wen Hu

a-Fe2O3 Nanostructures: Inorganic Salt-Controlled Synthesis and Their Electrochemical Performance toward Lithium Storage

J. Phys. Chem. C,2008, 112 (43), 16824–16829.

31. Qing-Shan Kong, Xing-Long Wu,Yu-Guo Guo, Yi-Qian Wang, Yan-Zhi Xia, Jian Yu, Hai-Hua Liu, Xiao-Feng Duan

Preparation of ZnO Nanostructures by Thermal Degradation of Zinc Alginate Fibers

ActaPhys. -Chim. Sin.,2008, 24(12), 2179-2184.

32. Yong-Sheng Hu,Yu-Guo Guo*, Robert Dominko, Miran Gaberscek, Janko Jamnik, Joachim Maier*

Improved electrode performance of porous LiFePO4 using RuO2 as an oxidic nanoscale interconnect

Adv. Mater.,2007, 19, 1963-1966.

33. Yu-Guo Guo, Yong-Sheng Hu, Wilfried Sigle, Joachim Maier

Superior Electrode Performance of Nanostructured Mesoporous TiO2 (Anatase) through Efficient Hierarchical Mixed Conducting Networks

Adv. Mater.,2007, 19, 2087-2091.

34. Yu-Guo Guo*, Jong-Sook Lee, Yong-Sheng Hu, Joachim Maier

AgI Nanoplates in Unusual 7H/9R Structures: Highly Ionically Conducting Polytype Heterostructures

J. Electrochem. Soc.,2007, 154 (9), K51-K60.

35. Yong-Sheng Hu,Yu-Guo Guo,*Wilfried Sigle, Sarmimala Hore, Palani Balaya, Joachim Maier*

Electrochemical lithiation synthesis of nanoporous materials with superior catalytic and capacitive activity

Nature Mater.,2006, 5(9), 713-717.

36. Yu-Guo Guo, Yong-Sheng Hu, Joachim Maier

Synthesis of hierarchically mesoporous anatase spheres and their application in lithium batteries

Chem. Commun.,2006,(26), 2783-2785.

37. Yu-Guo Guo*, Yong-Sheng Hu, Jong-Sook Lee, Joachim Maier

High-Performance Rechargeable All-Solid-State Silver Battery Based on Superionic AgI Nanoplates

Electrochem. Commun.,2006, 8(7), 1179-1184.

38. Yu-Guo Guo, Jong-Sook Lee, Joachim Maier

Preparation and characterization of AgI nanoparticles with controlled size, morphology and crystal structure

Solid State Ionics,2006, 177, 2467-2471.

39. Yong-Sheng Hu, Lorenz Kienle,Yu-Guo Guo, Joachim Maier

High lithium electroactivity of nano-sized rutile TiO2

Adv. Mater.,2006, 18(11), 1421-1426.

40. Yu-Guo Guo, Jong-Sook Lee, Joachim Maier

AgI nanoplates with mesoscopic superionic conductivity at room temperature

Adv. Mater.,2005,17(23), 2815-2819.

41. Yu-Guo Guo, Jin-Song Hu, Hui-Min Zhang, Han-Pu Liang, Li-Jun Wan, Chun-Li Bai

Sn/Pt bimetallic nanotube array and its electrocatalytic activity for methanol oxidation

Adv. Mater.2005, 17(6) 746-750.

42. Aninda J. Bhattacharyya, Jürgen Fleig,Yu-Guo Guo, Joachim Maier

Local conductivity effects in polymer electrolytes

Adv. Mater.,2005,17(21), 2630-2634.

43. Cong-Ju Li,Yu-Guo Guo, Bing-Shi Li, Chun-Ru Wang, Li-Jun Wan, Chun-Li Bai

Template synthesis of Sc@C82(I) nanostructures at room temperature

Adv. Mater.2005, 17(1), 71-73.

44. Yu-Guo Guo, Jin-Song Hu, Han-Pu Liang, Li-Jun Wan, Chun-Li Bai

TiO2-based composite nanotube arrays prepared by layer-by-layer assembly

Adv. Funct. Mater.2005, 15(2), 196-202.

45. Yu-Guo Guo, Hui-Min Zhang, Jin-Song Hu, Li-Jun Wan, Chun-Li Bai

Nanoarchitectured metal film electrodes with high electroactive surface areas

Thin Solid Films.2005, 484(1-2), 341-345.

46. Jin-Song Hu,Yu-Guo Guo, Han-Pu Liang, Li-Jun Wan, Li Jiang

Three-dimensional self-organization of supramolecular self-assembled porphyrin hollow hexagonal nanoprisms

J. Am. Chem. Soc.2005, 127, 17090-17095.

47. Han-Pu Liang,Yu-Guo Guo, Jin-Song Hu, Chuan-Feng Zhu, Li-Jun Wan, Chun-Li Bai

Ni-Pt multilayered nanowire arrays with enhanced coercivity and high remanence ratio

Inorg. Chem.,2005, 44(9), 3013-3015.

48. Jin-Song Hu, Ling-Ling Ren,Yu-Guo Guo, Han-Pu Liang, An-Min Cao, Li-Jun Wan, Chun-Li Bai

Mass-production and high photocatalytic activity of ZnS nanoporous nanoparticles

Angew. Chem. Int. Ed.,2005, 44(8), 1269-1273.

49. K. Xiao, Y. Liu,Yu-Guo Guo, G. Yu, L.J. Wan, D. Zhu

Influence of the self-assembly monolayers on the characteristics of copper phthalacyanine thin film transistor

Appl. Phys. A-Mater. Sci. Proce.,2005, 80 (7), 1541-1545.

50. Yu-Guo Guo, Li-Jun Wan, Cong-Ju Li, Dong-Min Chen, Chen Wang, Chun-Ru Wang, Chun-Li Bai, Yan-Guo Wang

The effects of annealing on the structures and electrical conductivities of fullerene-derived nanowires

J. Mater. Chem.2004, 14(5), 914-918.

51. Yu-Guo Guo, Li-Jun Wan, Chen Wang, Chun-Ru Wang, Chun-Li Bai, Liang-Bing Gan, Dong-Min Chen

Controlled fabrication of fullerene derivative one-dimensional nanostructures via electrophoretic deposition of its clusters

Chin. Sci. Bull.,2004, 49 (19), 2021-2025.

52. Han-Pu Liang,Yu-Guo Guo, Hui-Min Zhang, Jin-Song Hu, Li-Jun Wan, Chun-Li Bai

Controllable AuPt bimetallic hollow nanostructures

Chem. Commun.,2004, 1496-1497.

53. Jin-Song Hu,Yu-Guo Guo, Han-Pu Liang, Li-Jun Wan, Chun-Li Bai, Yan-Guo Wang

Interface assembly synthesis of inorganic composite hollow spheres

J. Phys. Chem. B2004, 108 (28), 9734-9738.

54. Yan Zhao,Yu-Guo Guo, Ya-Li Zhang

Fabrication and characterization of highly ordered Pt nanotubule arrays

Phys. Chem. Chem. Phys.2004, 6 (8), 1766-1768.

55. Han-Pu Liang, Hui-Min Zhang, Jin-Song Hu,Yu-Guo Guo, Li-Jun Wan, Chun-Li Bai

Pt hollow nanospheres: facile synthesis and enhanced electrocatalysts

Angew. Chem. Int. Ed.2004, 43, 1540-1543.

56. Yu-Guo Guo, Cong-Ju Li, Li-Jun Wan, Dong-Min Chen, Chun-Ru Wang, Chun-Li Bai, Yan-Guo Wang

Well-defined fullerene nanowire arrays

Adv. Funct. Mater.2003, 13(8), 626-630.

57. Yu-Guo Guo, Li-Jun Wan, C.-Feng Zhu, De-Liang Yang, Dong-Min Chen, Chun-Li Bai

Ordered Ni-Cu nanowire array with enhanced coercivity

Chem. Mater.2003, 15(3), 664-667.

58. Yu-Guo Guo, Jin-Song Hu, Han-Pu Liang, Li-Jun Wan, Chun-Li Bai

Highly dispersed metal nanoparticles in porous anodic alumina films prepared by a breathing process of polyacrylamide hydrogel

Chem. Mater.2003, 15(22), 4332-4336.

59. Yu-Guo Guo, Li-Jun Wan, and Chun-Li Bai

Gold/titania core/sheath nanowires prepared by layer-by-layer assembly

J. Phys. Chem. B2003, 107(23), 5441-5444.

60. Hui-Min Zhang,Yu-Guo Guo, Li-Jun Wan, Chun-Li Bai

Novel electrocatalytic activity in layered Ni-Cu nanowire arrays

Chem. Commun.2003, 3022-3023.

61. LY Zhao, XK Wang,Yu-Guo Guo, NZ Wu, YC Xie

Adsorption of methylene blue on the muscovite

ActaPhysico-Chimica Sinica,2003, 19(10), 896-901.

62. Dongsheng Xu, Guolin Guo,Yu-Guo Guo, Yali Zhang and Linlin Gui

Nanocrystal size control by bath temperature in electrodeposited CdSe thin films

J. Mater. Chem.2003, 13 (2), 360-364.

63. Yu-Guo Guo, Li-Jun Wan, Jian-Ru Gong and Chun-Li Bai

Preparation and dispersion of Ni-Cu composite nanoparticles

Phys. Chem. Chem. Phys.2002, 4(14), 3422-3424.

64. Dongsheng Xu,Yu-Guo Guo, Dapeng Yu, Guolin Guo, Youqi Tang

Highly ordered and well-oriented single-crystal CdTe nanowire arrays by direct-current electrodeposition

J. Mater. Res.2002, 17(7), 1711-1714.